1. | 파동 -입자 이원성, 슈뢰딩거 방정식 | |||
2. | 화학 원리의 중요성 | 1. An introduction to chemistry 2. General course information and policies for 5.111 3. Introduction of teaching staff |
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3. | 전자와 핵의 발견과 양자역학의 필요성 | 1. Discovery of electron and the nucleus 2. (Failure of) the classical description of the atom 3. An introduction to quantum mechanics |
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4. | 파동-빛의 분자 이중성 | 1. (Failure of) the classical description of the atom 2. Introduction to quantum mechanics: wave-particle duality 3. Light as a wave: characteristics of waves 4. Light as a particle: the photoelctric effect |
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5. | 수소원자 에너지 레벨 | The Hydrogen Atom 1. Binding energy of the electron to the nucleus 2. Verification of hydrogen-atom energy levels A. Photon emission B. Photon absorption 3. Wavefunctions (orbitals) for the hydrogen atom |
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6. | 수소원자 파동함수(오비탈) | Hydrogen Atom Wavefunctions 1. Wavefunctions (orbitals) for the hydrogen atom 2. shapes of H-atom wavefunctions: s orbitals 3. Radial probability distributions |
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7. | p-오비탈 | The Hydrogen Atom 1. Radial probability distributions for s-orbitals 2. p-orbitals A. The shape of p-orbitals B. Radial probability distributions Multi-electron Atoms 3. Electron spin 4. Wavefunctions for multielectron atoms |
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8. | 다전자원자와 전자 배열 | Multi-electron Atoms 1. Wavefunctions for multi-electron atoms 2. Binding energy 3. Electron configurations(Aufbau principle) 4. Photoelectric spectroscopy |
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9. | 주기율 경향 | 1. Photoelectric spectroscopy 2. Periodic table/ periodic trends A. Ionization energy B. Electron affinity C. Electronegativity D. Atomin rsdius 3. Isoelectronic atomes/ions |
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10. | 주기율 경향 계속 : 공유 결합 | Finish exam 1 material: 1.Atomin rsdius and Isoelectronic atomes/ions Exam 2 material: 2. Covalent bonds 3. Lewis structures |
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11. | 루이스 구조식 | Lewis structures | ||
12. | 루이스 구조식 법칙의 예외 : 이온 결합 | 1. Breakdown of the octet rule case1. Odd number of valence electrons case2. Octet deficient molecules case3. Valence shell expansion 2. Iinic bonds 3. Polar covalent bonds |
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13. | 극성 공유 결합: VSEPR 이론 | 1. Polar covalent bonds and polar molecules 2. The shapes of molecules: VESPR theory A. Molecules without lone pairs B. Molecules with lone pairs |
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14. | 분자 오비탈 이론 | Molecules orbital theory 1. Bonding and antibonding orbitals 2. Homoneclear diaomic molecules A. Molecules with MO's originating from a orbitals B. Molecules with MO's originating from a and p orbitals 3. Heteronuclear diatomic molecules |
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15. | 원자가 결합 이론과 교잡 | Molecules orbital theory Valence bond theory and hybridization 1. Sigma and pi bonds 2. Hybridization of atomic orbitals 3. Hybridization in complex molecules |
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16. | 복합분자의 교잡 측정: 열화학 과 결합 에너지/ 결합 엔탈피 | 1.Valence bond theory and hybridization Determining hybrization in complex molecules 2.Energies and enthalpies of chemical reaction A. Bond energy/ bond enthalpy B. Heat of formation |
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17. | 엔트로피와 무질서 | Thermodynamics 1. Enthalpies of chemical reactions 2. Spontaneous change and free energy 3. Entropy 4. Free energy of formation |
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18. | 자유에너지와 자발성의 억제 | Thermodynamics 1. Free energy do formation 2. Effect of temperature on spontaneity 3. Thermodynamics in biological systems A) ATP-coupled reactions B) Hydrogen bonding |
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19. | 화학 평형 | Nature of Chemical Equilibrium Meaning of K Relationshil between Equilibrium Expressions External effects on K |
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20. | 르 샤틀리에의 원리와 혈액에 산소 레벨의 적용 | Changing the volume | ||
21. | 산-염기 평형: MIT물은 마시기에 안전한가? | Classification of Acid-Bases, Autoionization of Water, pH Function, Strength of Acids and Bases, Equilibrium Involving Weak Acids. | ||
22. | 화학과 생물학의 완충기 | Equilibrium involving weak bases, pH of salt solutions, and buffers | ||
23. | 산-염기 적정 | Topic: Titrations | ||
24. | 산화/환원 | Topics: Oxidation States, and Balancing Oxidation/Reduction Reactions (Read Section K) | ||
25. | 전기화학적 세포 | Topics:Electrochemical Cells, Faraday's Law, and the Relationship between Gibbs Free Energy and Cell Potential | ||
26. | 화학과 생물학적 산화/ 환원 | Topics: Adding and Subtracting Half-Cell Reactions and Nernst Equation | ||
27. | 전이와 납중독 처리 | Topics: Formation of coordination complexes, coordination number, coordination complex notation, structures of coordination complexes, chelate effect, isomers, d- electron counting, and d-orbitals. |
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28. | 결정 전기장 이론 | Crystal field and ligand field theories | ||
29. | 생물학에의 금속 | Crystal Field Theory Continued, and Magnetism | ||
30. | 자성과 분광화학의 이론 | Crystal Field Theory and the Spectrochemical Series. | ||
31. | 비율 법칙 | Rates of Chemical Reactions and Rate Law | ||
32. | 핵 화학과 핵 반응 | Radioactive Decay, Second Order Integrated Rate Laws, Kinetics and Chemical Equilibrium, Introduction to Reaction Mechanisms | ||
33. | 반응 메카니즘 | Reaction Mechanisms | ||
34. | 온도와 동역학 | Effect of Temperature, Collision Theory, Activated Complex Theory. | ||
35. | 효소 촉매작용 | Topic: Catalysis | ||
36. | 생화학 | Review of Topics : Chemical Equilibrium, Acid Base, Oxidation Reduction, Transition Metals, and Kinetics |